Elementary Principles of Chemical Processes, 4e Reserve Problems Abridged Loose-leaf Print Companion
Book details
Summary
Description
About the Authors iii
Preface to the Fourth Edition iv
Notes to Instructors v
Digital Resources and WileyPLUS vii
Postscript: Introduction to an Author viii
Nomenclature ix
Glossary xi
PART 1 Engineering Problem Analysis 1
CHAPTER 1 What Some Chemical Engineers Do for a Living 3
CHAPTER 2 Introduction to Engineering Calculations 5
2.0 Learning Objectives 5
2.1 Units and Dimensions 6
2.2 Conversion of Units 7
2.3 Systems of Units 8
2.4 Force and Weight 10
2.5 Numerical Calculation and Estimation 12
2.6 Dimensional Homogeneity and Dimensionless Quantities 19
2.7 Process Data Representation and Analysis 21
2.8 Summary 29
CHAPTER 3 Processes and Process Variables 31
3.0 Learning Objectives 31
3.1 Mass and Volume 32
3.2 Flow Rate 34
3.3 Chemical Composition 36
3.4 Pressure 43
3.5 Temperature 50
3.6 Summary 53
PART 2 Material Balances 55
CHAPTER 4 Fundamentals of Material Balances 57
4.0 Learning Objectives 57
4.1 Process Classification 58
4.2 Balances 59
4.3 Material Balance Calculations 63
4.4 Balances on Multiple-Unit Processes 82
4.5 Recycle and Bypass 88
4.6 Chemical Reaction Stoichiometry 95
4.7 Balances on Reactive Processes 106
4.8 Combustion Reactions 127
4.9 Some Additional Considerations about Chemical
Processes 135
4.10 Summary 138
CHAPTER 5 Single-Phase Systems 140
5.0 Learning Objectives 141
5.1 Liquid and Solid Densities 142
5.2 Ideal Gases 144
5.3 Equations of State for Nonideal Gases 152
5.4 The Compressibility-Factor Equation of State 159
5.5 Summary 166
CHAPTER 6 Multiphase Systems 167
6.0 Learning Objectives 169
6.1 Single-Component Phase Equilibrium 170
6.2 The Gibbs Phase Rule 176
6.3 Gas-Liquid Systems: One Condensable Component 178
6.4 Multicomponent Gas-Liquid Systems 184
6.5 Solutions of Solids in Liquids 193
6.6 Equilibrium between Two Liquid Phases 201
6.7 Adsorption on Solid Surfaces 205
6.8 Summary 208
PART 3 Energy Balances 211
CHAPTER 7 Energy and Energy Balances 213
7.0 Learning Objectives 214
7.1 Forms of Energy: The First Law of Thermodynamics 215
7.2 Kinetic and Potential Energy 217
7.3 Energy Balances on Closed Systems 218
7.4 Energy Balances on Open Systems at Steady State 220
7.5 Tables of Thermodynamic Data 225
7.6 Energy Balance Procedures 230
7.7 Mechanical Energy Balances 233
7.8 Summary 238
CHAPTER 8 Balances on Nonreactive Processes 240
8.0 Learning Objectives 240
8.1 Elements of Energy Balance Calculations 241
8.2 Changes in Pressure at Constant Temperature 249
8.3 Changes in Temperature 250
8.4 Phase-Change Operations 262
8.5 Mixing and Solution 281
8.6 Summary 292
CHAPTER 9 Balances on Reactive Processes 295
9.0 Learning Objectives 296
9.1 Heats of Reaction 296
9.2 Measurement and Calculation of Heats of Reaction: Hess''s Law 301
9.3 Formation Reactions and Heats of Formation 303
9.4 Heats of Combustion 305
9.5 Energy Balances on Reactive Processes 306
9.6 Fuels and Combustion 321
9.7 Summary 331
CHAPTER 10 Balances on Transient Processes 334
10.0 Learning Objectives 334
10.1 The General Balance Equation . . . Again 334
10.2 Material Balances 339
10.3 Energy Balances on Single-Phase Nonreactive Processes 346
10.4 Simultaneous Transient Balances 351
10.5 Summary 354
APPENDIX A Computational Techniques 357
A.1 The Method of Least Squares 357
A.2 Iterative Solution of Nonlinear Algebraic Equations 360
A.3 Numerical Integration 373
APPENDIX B Physical Property Tables 377
B.1 Selected Physical Property Data 378
B.2 Heat Capacities 385
B.3 Vapor Pressure of Water 388
B.4 Antoine Equation Constants 390
B.5 Properties of Saturated Steam: Temperature Table 392
B.6 Properties of Saturated Steam: Pressure Table 394
B.7 Properties of Superheated Steam 400
B.8 Specific Enthalpies of Selected Gases: SI Units 402
B.9 Specific Enthalpies of Selected Gases: U.S. Customary Units 402
B.10 Atomic Heat Capacities for Kopp''s Rule 403
B.11 Integral Heats of Solution and Mixing at 25°C 403
Index 404
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