9780195074949-0195074947-Unimolecular Reaction Dynamics: Theory and Experiments (International Series of Monographs on Chemistry)

Unimolecular Reaction Dynamics: Theory and Experiments (International Series of Monographs on Chemistry)

ISBN-13: 9780195074949
ISBN-10: 0195074947
Edition: Illustrated
Author: Baer, Tomas, Hase, William L.
Publication date: 1996
Publisher: Oxford University Press
Format: Hardcover 448 pages
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Book details

ISBN-13: 9780195074949
ISBN-10: 0195074947
Edition: Illustrated
Author: Baer, Tomas, Hase, William L.
Publication date: 1996
Publisher: Oxford University Press
Format: Hardcover 448 pages

Summary

Acknowledged authors Baer, Tomas, Hase, William L. wrote Unimolecular Reaction Dynamics: Theory and Experiments (International Series of Monographs on Chemistry) comprising 448 pages back in 1996. Textbook and eTextbook are published under ISBN 0195074947 and 9780195074949. Since then Unimolecular Reaction Dynamics: Theory and Experiments (International Series of Monographs on Chemistry) textbook was available to sell back to BooksRun online for the top buyback price or rent at the marketplace.

Description

This book provides a penetrating and comprehensive description of energy selected reactions from a theoretical as well as experimental view. Three major aspects of unimolecular reactions involving the preparation of the reactants in selected energy states, the rate of dissociation of the activated molecule, and the partitioning of the excess energy among the final products, are fully discussed with the aid of 175 illustrations and over 1,000 references, most from the recent literature. Examples of both neutral and ionic reactions are presented. Many of the difficult topics are discussed at several levels of sophistication to allow access by novices as well as experts. Among the topics covered for the first time in monograph form is a discussion of highly excited vibrational/rotational states and intramolecular vibrational energy redistribution. Problems associated with the application of RRKM theory are discussed with the aid of experimental examples. Detailed comparisons are also made between different statistical models of unimolecular decomposition. Both quantum and classical models not based on statistical assumptions are described. Finally, a chapter devoted to the theory of product energy distribution includes the application of phase space theory to the dissociation of small and large clusters. The work will be welcomed as a valuable resource by practicing researchers and graduate students in physical chemistry, and those involved in the study of chemical reaction dynamics.

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